The peculiarities of hardening of composite anhydrite cement pozzolanna binding material with not burned natural anhydrite

Abstract

The comparative investigations of gypsum cement pozzolana binding materials (GCPB) and anhydrite cement pozzolana binding materials (ACPB) with not burned natural anhydrite were performed controlling kinetics of hardening, phase composition of new formations generated in the course of hardening, structure, mechanical strength and water resistance. It was established that the component of natural anhydrite with compact crystalline structure provides specific properties to ACPB, i. e. long-term hardening, low porosity of the hardened matrix and good hydraulic properties. At the same plasticity of moulding mix, ACPB density was higher by approximately 25 % than that of GCPB. ACPB early strength is lower than GCPB, however, the gradual hydration of anhydrite over time makes the ACPB hardening structure more compact and stronger. After 28 days ACPB strength was higher by ~11 %, after 4 months ~by 23 %, after 7 months by ~30 % than that of GCPB. During the ACPB hardening, the slower generating new formations of dihydrate gypsum together with new formations of cement hydration make the hardening structure considerably more water resistant. Contrary to GCPB, the hardened ACPB does not loose strength in water, but is developing it further. The process of anhydrite hydration in the hardening ACPB is proceeding for many years and over time its influence on ACPB strength becomes greater than that of cementitious component. It was established that ACPB still contains non- hydrated anhydrite after 15 years of hardening. Basing on the results of investigations the performance characteristics of composite anhydrite binding materials with not burned natural anhydrite were predicted, as well as a possibility to replace cement binding materials by them.

Lėčiau susidarantys dihidračio gipso naujadarai kartu su cemento hidratacijos naujadarais formuoja tankią atsparią vandens poveikiui kietėjimo struktūrą ir sukietėjusi ACPB, priešingai nei GCPB, vandenyje ne tik nepraranda stiprumo, bet ir stiprėja toliau. Pagal kietėjimo pobūdį, stiprį bei hidraulines savybes ACPB su gamtiniu anhidritu yra artima cementinėms rišamosioms medžiagos ir tam tikrose srityse galėtų jas pakeisti. Kadangi didžiąją ACPB dalį sudaro nedegto gamtinio anhidrito milteliai, ją naudojant sumažėtų energijos sąnaudos bei CO2 išlakos ir tai prisidėtų prie šiltnamio efekto mažinimo bei energijos taupymo programų vykdymo.